10/22/08
Polymer nanocomposites
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The use of polymer-clay nanocomposites for flame retardant applications is becoming more common, especially as it is realized that the clay nanocomposite can replace part of the flame retardant package while maintaining fire safety ratings at a lower flame retardant loading. This results in a better balance of properties for the nanocomposite material compared to the non-nanocomposite flame retardant product, and in some cases, better cost for the flame retardant resin, especially if the organoclay is cheaper than the flame retardant which it replaces. It should be noted that the organoclay can replace traditional flame retardant on more than a 1:1 by weight basis, meaning 1 g of organoclay can replace more than 1 g of traditional flame retardant, resulting in a lighter material. In fact, it appears that clay nanocomposite systems serve as a nearly universal synergist for flame retardant additives, with some exceptions.
Another common application of clay nanocomposites is for gas-barrier materials. Clay nanoparticles create a complex network in the polymer matrix, such that various gases either diffuse very slowly or not at all through polymer chains and pinholes in thin films or thicker polymer parts. The success of clay nanocomposites to impart decreased diffusivity of oxygen and water has led to their use in food/liquid packaging to keep foods fresher longer.
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